Corrosion behavior of T91 steel in liquid lead-bismuth eutectic at 550 ℃ under different tensile stresses
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Abstract
To efficiently evaluate the corrosion behavior of T91 steel in lead-bismuth eutectic (LBE) under different stresses, a corrosion experiment of small tapered conical specimen of T91 in LBE with an oxygen concentration of 1×10-6 wt% at 550 ℃ under 0~180 MPa was carried out. The results showed that the (Fe,Cr)3O4 and internal oxidation zone always exist, but the Fe3O4 peels off severely under tensile stress, and its fragments become smaller with the increase of stress; (Fe,Cr)3O4 has two sub-layers, which is caused by different Cr enrichments; As the tensile stress increases, the cracks increase in number and size, extending continuously to the matrix direction, running through the whole (Fe,Cr)3O4 by the time the tensile stress reaches 180 MPa. Moreover, with the tensile stress increasing, the thickness of each oxide layer increases, but the rate of incrassation decreases constantly.
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